Wave Function Identity: A New Symmetry for 2-Electron Systems in an Electromagnetic Field
Stationary-state Schrödinger-Pauli theory is a description of electrons with a spin moment in an external electromagnetic field. For 2-electron systems as described by the Schrödinger-Pauli theory Hamiltonian with a symmetrical binding potential, we report a new symmetry operation of the electronic coordinates. The symmetry operation is such that it leads to the equality of the transformed wave function to the wave function. This equality is referred to as the Wave Function Identity. The symmetry operation is a two-step process: an interchange of the spatial coordinates of the electrons whilst keeping their spin moments unchanged, followed by an inversion.
Slamet, M., & Sahni, V. (2022). Wave function identity: A new symmetry for 2-electron systems in an electromagnetic field. Chemical Physics, 556 (111453). Doi: 10.1016/j.chemphys.2022.111453