Molten Lithium Carbonate—Sodium Carbonate—Potassium Carbonate Eutectic: The Reaction of Four Lanthanide(III) Chlorides
Document Type
Article
Publication Date
3-1985
Abstract
Cerium(III) chloride reacted with carbonate in the solid state under a carbon dioxide atmosphere, to form cerium(IV) oxide, while europium(III) chloride, praseodymium(III) chloride and lanthanum(III) chloride underwent anion exchange and partial decomposition to give the dioxymonocarbonates initially. The latter three compounds took up carbon dioxide as the temperature increased, the amount varying in accordance with the basicity of the cations ( ="20" border="0" style="vertical-align:bottom" width="8" alt="View the MathML source" title="View the MathML source" src="http://origin-ars.els-cdn.com/content/image/1-s2.0-0040603185853703-si1.gif">
, eight="20" border="0" style="vertical-align:bottom" width="8" alt="View the MathML source" title="View the MathML source" src="http://origin-ars.els-cdn.com/content/image/1-s2.0-0040603185853703-si2.gif">
and 1 mole of CO2 per mole of Ln2O2CO3, respectively), as did the temperatures of reaction.
DOI
http://dx.doi.org/10.1016/0040-6031(85)85370-3
Recommended Citation
Habboush, D. A., D. H. Kerridge and S. A. Tariq. "Molten Lithium Carbonate—Sodium Carbonate—Potassium Carbonate Eutectic: The Reaction of Four Lanthanide(III) Chlorides." Thermochimica Acta 84.1 (1985): 13-18.
Comments
Published: Habboush, D. A., D. H. Kerridge and S. A. Tariq. "Molten Lithium Carbonate—Sodium Carbonate—Potassium Carbonate Eutectic: The Reaction of Four Lanthanide(III) Chlorides." Thermochimica Acta 84.1 (1985): 13-18.